Phase transition in waters with different content of deuterium

According to kinetics of temperature changes and laser light scattering on density heterogeneities we investigated waters with different content of deuterium in the area of their phase transition. It has been found out that protium/deuterium ratio substantially affects the process of phase transition water-ice-water in non-equilibrium conditions (the rate of temperature changes—2°C/min): temperature of light water ice melting (D/H = 4.2 ppm) constitutes 1.1 ± 0.3°C against 0.0 ± 0.3°C for high ohmic deionized water (D/H = 140 ppm) and 3.8 ± 0.3°C—for heavy one. Determined are special features of changes in phase state of water on the basis of concepts about water as a colloid system containing deuterium and stabilized gigantic heterophase clusters. © 2015, Allerton Press, Inc.

Авторы
Goncharuk V.V. 1 , Taranov V.V. 1 , Kurlyantseva A.Y.1 , Syroeshkin A.V. 2
Номер выпуска
5
Язык
Английский
Страницы
219-223
Статус
Опубликовано
Том
37
Год
2015
Организации
  • 1 Dumanskii Institute of Colloid Chemistry and the Chemistry of Water, National Academy of Sciences of Ukraine, Kiev, Ukraine
  • 2 University of Peoples’ Friendship, Moscow, Russian Federation
Ключевые слова
clusters; heavy water; light water; optical density; optical heterogeneities; phase transition water-ice-water; temperature
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