Constants of acid-base equilibria at the ZrO2/electrolyte interface

Acid-base equilibria arising at the zirconium oxide/electrolyte interface were studied experimentally using potentiometric titration and analysis of the dependence of the electrokinetic potential on the pH value in aqueous solutions of potassium chloride of various concentrations. The equilibrium constants were calculated. It was found that the two methods give consistent values of acid-base equilibrium constants: pK0 1 = 4.0, pK0 2 = 9.2, pK0 3 = 6.2, and pK0 4 = 6.7.

Авторы
Batrakov V.V.1 , Khlupov A.Yu.1 , Gorichev I.G.1 , Kostrikin A.V. 2 , Izotov A.D.3
Номер выпуска
SUPPL. 3
Язык
Английский
Страницы
S553-S558
Статус
Опубликовано
Том
74
Год
2000
Организации
  • 1 Moscow State Pedagogical University, ul. Malaya Pirogovskaya 1, Moscow, 119882, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow DSP, 119882, Russian Federation
  • 3 Inst. of Gen. and Inorg. Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117071, Russian Federation
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/412/