Molecular theory of graphene chemical modification

The chapter is devoted to the chemical uniqueness of graphene. In view of molecular theory, the uniqueness is a consequence of benzenoid packing of carbon atoms, based on three neighbors to each carbon atom leaving the atom fourth valence electron (the odd one) on its own. Due to rather large C-C distances, the odd electrons of graphene molecules are correlated whereupon the molecules are radicalized, and molecular chemistry of graphene is the chemistry of "dangling bonds." The chapter presents the description of the molecular-theorydangling- bond view on graphene molecule hydrogenation and oxidation. Specific peculiarities of the graphene molecular chemistry related to size-dependent topochemical features are discussed, as well. © 2016 by Taylor & Francis Group, LLC.

Авторы
Редакторы
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Издательство
CRC Press
Номер выпуска
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Язык
Английский
Страницы
317-340
Статус
Опубликовано
Подразделение
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Ссылка
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DOI
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Номер
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Том
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Год
2016
Организации
  • 1 Department of Theoretical Physics and Mechanics, People's Friendship University of Russia, Moscow, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/3953/