Hydrohydrazination of Arylalkynes Catalyzed by an Expanded Ring N-Heterocyclic Carbene (er-NHC) Gold Complex under Solvent-Free Conditions

[(THD-Dipp)AuOTf], supported by the strongly electron donating, sterically bulky THD-Dipp (1,3-bis(2,6-diisopropylphenyl)hexahydro-2H-1,3-diazepine-2-ylidene) seven-membered N-heterocyclic carbene ligand, efficiently promotes intermolecular addition of Ts- and Boc-hydrazine to arylalkynes under solvent-free conditions. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Авторы
Morozov O.S.1 , Gribanov P.S.1 , Asachenko A.F.1, 2 , Dorovatovskii P.V.3 , Khrustalev V.N. 4, 5 , Rybakov V.B.6 , Nechaev M.S.1, 2, 6
Журнал
Advanced Synthesis and Catalysis
Издательство
Wiley-VCH Verlag
Номер выпуска
9
Язык
Английский
Страницы
1463-1468
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1002/ADSC.201500658
Том
358
Год
2016
Организации
  • 1 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, Moscow, 119991, Russian Federation
  • 2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, 119991, Russian Federation
  • 3 NRC Kurchatov Institute, Acad. Kurchatov Square 1, Moscow, 123182, Russian Federation
  • 4 Department of Inorganic Chemistry, Peoples' Friendship University of Russia, Miklukho-Maklay Street 6, Moscow, 117198, Russian Federation
  • 5 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, Moscow, 119991, Russian Federation
  • 6 M. V. Lomonosov Moscow State University, Leninskie Gory 1 (3), Moscow, 119991, Russian Federation
Ключевые слова
alkynes; gold; hydrazine; hydroamination; N-heterocyclic carbenes
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