Complexes of some tervalent metals with N-alkyl(benzyl)nitrozohydroxylamine derivatives

Twenty two new complexes of some tervalent metals (aluminum, chromium, iron, and lanthanides) with nitrozohydroxylamine N-alkyl(benzyl) derivatives ML3 m · nH2O, (m = 1‒5) were synthesized and isolated in a crystalline state. The crystal and molecular structures of the iron(III) complex with N-(2-fluorobenzyl)-N-nitrozohydroxylamine were determined by X-ray diffraction. An octahedral coordination of the central ion and a bidentate chelating coordination of the organic ligand were established. The spectral criteria of coordination of nitrozohydroxylamine alkyl(benzyl) derivatives were determined, and the complexation processes in solutions were studied. © 2016, Pleiades Publishing, Ltd.

Авторы
Kovalchukova O.V. 1 , Namichemazi N. 1 , Bostanabad A.S.2 , Stash A.I. 3 , Strashnova S.B. 1 , Zuzin I.N.4
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
6
Язык
Английский
Страницы
718-725
Статус
Опубликовано
Подразделение
-
Номер
-
Том
61
Год
2016
Организации
  • 1 People’s Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 2 University of Tabriz, Tabriz, Iran
  • 3 Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 103064, Russian Federation
  • 4 Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russian Federation
Ключевые слова
Complexation; Crystalline materials; Synthesis (chemical); X ray diffraction; Complexation process; Crystal and molecular structure; Crystalline state; Octahedral coordination; Organic ligands; Spectral criteria; Iron compounds
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/3920/