Mesoporous Hierarchically Hollow Flower-Like CoAl-LDH@N,S-doped Graphene@Pd Nanoarchitectures for Heck Couplings

Abstract: A smart strategy for the synthesis of hierarchical CoAl-LDH hollow spheres assembled with nitrogen and sulfur co-doped graphene for high holding of palladium nanoparticles (CoAl-LDH@N,S-G@Pd) is reported. This architecture exhibited excellent activity in Heck reactions with TOF as high as 1633 h−1 due to a strong metal–support interaction, good electron transfers and high surface area. Graphic Abstract: [Figure not available: see fulltext.]. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.