3,3,6,7-Tetramethyl-1-N-(1-phenyl-2,3-dimethyl-5-oxo-3-pyrazolin-4-yl) imino-1,2,3,4-tetrahydroisoquinolinium Trichlorocobaltate: Synthesis, Crystal Structure, and Spectra

The product of the reaction between cobalt(II) chloride and 3,3,6,7-tetramethyl-1-N-(1-phenyl-2,3-dimethyl-5-oxo-3-pyrazolin-4-yl)imino-1,2, 3,4-tetrahydroisoquinoline (L1) was synthesized and characterized by X-ray diffraction and IR and electronic absorption spectroscopy. In the compound [(HL1)CoCl3], the protonated monodentate ligand (HL1)+ is coordinated to the cobalt atom through the oxygen atom. In the cobalt coordination tetrahedron, the Co-Cl bond lengths are 2.227, 2.276, and 2.286 Å; the Co-O bond length is 1.998 Å.

Авторы
Sokol V.I.1 , Davydov V.V. 2 , Sergienko V.S.1 , Merkur'eva Yu.N. 2 , Ryabov M.A. 2 , Shklyaev Yu.V.3 , Korchevoi S.M.1
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
2
Язык
Английский
Страницы
226-232
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
46
Год
2001
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/378/