1-Morpholino-3,3-Dimethyl-3,4-Dihydroisoquinoline and Its Complexes with Cobalt(II) and Copper(II) Chlorides: Synthesis and X-Ray Structural and Spectroscopic Study

1-Morpholino-3,3-dimethyl-3,4-dihydroisoquinoline (L) and its complexes with cobalt(II) and copper(II) chlorides of the (LH)2[MCl4] composition were synthesized. The structures of the compounds were studied by X-ray crystallography and electronic and IR spectroscopy. The isostructural complexes (LH)2[ML4], where M = Co2+ or Cu2+, have the cation-anion structure. The organic ligand HL+ with a proton at the nitrogen atom of the dihydroisoquinoline moiety is linked to the [MCl4]2- through the N-H⋯Cl hydrogen bond.

Авторы
Sokol V.I.1 , Ryabov M.A. 2 , Merkur'eva N.Yu. 2 , Sergienko V.S.1 , Shklyaev Yu.V.3 , Davydov V.V. 2
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
2
Язык
Английский
Страницы
233-240
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
46
Год
2001
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/376/