Interaction of Cobalt(II) Chloride with 1-(3,3-Dimethyl-3,4-dihydroisoquinolin-1-yl)-1-(quinolin-2-yl)-methane (L1): The Crystal Structure of the Complex [CoCl2(L1*=L1*)CoCl2] · H2O

The [CoCl2(L1*=L1*)CoCl2] · H2O complex (I) was synthesized by a reaction of CoCl2 with 1-(3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)-1-(quinolin-2-yl)methane (L1) and characterized using electronic absorption and IR spectroscopies and X-ray crystallography. The structure of this compound contains a binuclear complex molecule (on axis 2) and a condensed tetradentate bridging L1*=L1* ligand with a tetrasubstituted ethylene group. The coordination polyhedron of the Co atom is a distorted tetrahedron (Co-N, 2.059 and 2.075 Å; Co-Cl, 2.222 and 2.230 Å).

Авторы
Sokol V.I.1 , Davydov V.V. 2 , Elekhina N.A. 2 , Shklyaev Yu.V.3 , Sergienko V.S.1
Редакторы
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Издательство
IAPC Nauka/Interperiodica
Номер выпуска
1
Язык
Английский
Страницы
69-76
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
46
Год
2001
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 2 University of Peoples' Friendship, ul. Miklukho-Maklaya, 6, Moscow GSP, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Science, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/369/