Synthesis and molecular structure of functionalized tris[2-(4′-substituted butoxyphenyl)]phosphine oxides as precursors of tripodal ligands

A series of tris[2-(4′-substituted butoxyphenyl)]phosphine oxides [2-X(CH2)4OC6H4]3PO (X = OAc (2), OH (3), OSO2Me (4), Br (5), and N3 (6)) useful as precursors of new tripodal ligands have been prepared. Alkylation of initial tris(2-hydroxyphenyl)phosphine oxide (1) resulted in triacetate 2, which was deprotected to triol 3. The latter has been converted into trimesylate 4, which has been treated with LiBr or NaN3 to give the corresponding tribromo or triazido derivatives 5 and 6, respectively. According to X-ray diffraction, the molecules of compounds 2, 5, and 6 in crystal adopt conformation where two side arms are oriented to the same direction as the P=O group, while the third side arm is oriented in the opposite manner. © 2018 Wiley Periodicals, Inc.

Авторы
Baulina T.V.1 , Kudryavtsev I.Y.1 , Smolyakov A.F. 1, 2 , Pasechnik M.P.1 , Brel V.K.1
Журнал
Издательство
Wiley-Blackwell
Номер выпуска
4
Язык
Английский
Статус
Опубликовано
Номер
e21454
Том
29
Год
2018
Организации
  • 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation
  • 2 Faculty of Science, RUDN University, Moscow, Russian Federation
Ключевые слова
functionalized tris[2-(4′-substituted butoxyphenyl)]phosphine oxides; precursors of tripodal ligands; synthesis
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