Mimicking the bioelectrocatalytic function of recombinant CotA laccase through electrostatically self-assembled bioconjugates

Unprecedented 3D nanobiosystems composed of recombinant CotA laccases and citrate-stabilised gold nanoparticles have been successfully achieved by an electrostatic self-assembly strategy. The bioelectrochemical reduction of O2 driven by CotA laccase at the spore coat was mimicked. Consequently key insights into its bioelectrocatalytic function were unravelled. © The Royal Society of Chemistry.

Авторы
Alba-Molina D.1 , Rodríguez-Padrón D.2 , Puente-Santiago A.R.2 , Giner-Casares J.J.1 , Martín-Romero M.T.1 , Camacho L.1 , Martins L.O.3 , Muñoz-Batista M.J.2 , Cano M.1 , Luque R. 1, 2, 4
Журнал
Nanoscale
Издательство
Royal Society of Chemistry
Номер выпуска
4
Язык
Английский
Страницы
1549-1554
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1039/c8nr06001k
Том
11
Год
2019
Организации
  • 1 Departamento de Química Física y Termodinamica Aplicada, Instituto Universitario de Investigación en Química Fina y Nanoquímica IUIQFN, Facultad de Ciencias, Universidad de Córdoba, Campus de Rabanales, Ed. Marie Curie, Córdoba, E-14071, Spain
  • 2 Departamento de Química Orgánica, Instituto Universitario de Investigación en Química Fina y Nanoquímica IUIQFN, Facultad de Ciencias, Universidad de Córdoba, Campus de Rabanales, Ed. Marie Curie, Córdoba, E-14071, Spain
  • 3 Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Av da Republica, Oeiras, 2780-157, Portugal
  • 4 Peoples Friendship University of Russia (RUDN University) 6 Miklukho-Maklaya Str. 117198, Moscow, Russian Federation
Ключевые слова
Gold nanoparticles; Self assembly; Bioconjugates; Bioelectrocatalytic functions; Bioelectrochemical reductions; Electrostatic self assembly; Laccases; Nanobiosystems; Enzymes
Дата создания
04.02.2019
Дата изменения
04.02.2019
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/36079/
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