Statistical mechanical study of thermodynamic properties of a family of fullerites from C36 to C96 in the equilibrium with their vapors

The temperature dependence of saturated vapor pressure of fullerites C36-C96 and their thermodynamic properties along with the sublimation curves up to the spinodal are calculated. The saturated vapor pressures along all the range of temperatures are approximated by logPsat = A - (B/T) - CT. The coefficient A practically does not depend on the number of atoms in the molecule (varying only by 2.2%), B increases noticeably while C decreases from the C36 to the C96, both of them by approximately two. The isothermal bulk modulus BT and the shear modulus C44 vanish at the spinodal points. © 2004 Taylor & Francis Group, LLC.

Авторы
Редакторы
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Сборник материалов конференции
Издательство
-
Номер выпуска
1-2
Язык
Английский
Страницы
505-511
Статус
Опубликовано
Подразделение
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Ссылка
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Номер
-
Том
12
Год
2005
Организации
  • 1 Department of Theoretical Physics, Russian Peoples' Friendship University, Moscow, 117198, Russian Federation
  • 2 Instituto de Física, Universidade Federal de Goiás, C.P. 131, Goiânia, GO, 74001-970, Brazil
  • 3 Rosinter Restaurants Ltd., Moscow, Russian Federation
Ключевые слова
Equilibrium with vapors; Fullerites C36-C96; Thermodynamic properties
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/3519/