Slow hindered rotation of CF3 group in radical anion of ortho nitrobenzotrifluoride in N,N′-dimethylformamide and reconstruction of EPR spectrum

The temperature dependence of the EPR spectrum of the 2-CF3-C6H4-NO*2 radical anion in anhydrous N,N′-dimethylformamide, caused by hindered internal rotation of the CF3 group with an extreme activation energy of 34700 J·mol-1, was experimentally studied and reconstructed. © 2007 by Allerton Press, Inc.

Авторы
Polenov E.A.1 , Shundrin L.A.2 , Melnikov P.V.1 , Bozhenko K.V. 3
Редакторы
-
Сборник материалов конференции
Издательство
-
Номер выпуска
8
Язык
Английский
Страницы
1268-1273
Статус
Опубликовано
Подразделение
-
Ссылка
-
DOI
-
Номер
-
Том
70
Год
2006
Организации
  • 1 Lomonosov State Academy of Fine Chemical Technology, Moscow 117571, Russian Federation
  • 2 Novosibirsk Institute for Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090, Russian Federation
  • 3 Peoples Friendship University of Russia, Moscow 117198, Russian Federation
Ключевые слова
Activation energy; Fluorine compounds; Negative ions; Paramagnetic resonance; Temperature; Internal rotation; Nitrobenzotrifluoride; Radical anion; Nitrobenzene
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/3313/