Prins reaction under manganese dioxide control: The synthesis of 6-oxa-2-azabicyclo[3.2.1]octan-4-ones from tetrahydropyridines and formaldehyde

The course of the acid-catalysed Prins reaction of tetrahydropyridines 1 with formaldehyde, leading to derivatives of piperidino-dioxane 4 and 3-oxa-7-azabicyclononanes 5 and 6, is dramatically changed in the presence of manganese dioxide to give new products, 6-oxa-2-azabicyclo[3.2.1]octan-4-ones 7 and 8.

Редакторы
-
Издательство
Royal Society of Chemistry
Номер выпуска
1
Язык
Английский
Страницы
27-29
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
11
Год
2001
Организации
  • 1 Peoples' Friendship Univ. of Russia, 117198 Moscow, Russian Federation
Ключевые слова
3 oxa 7 azabicyclononane; 6 oxa 2 azabicyclo[3.2.2]octan 4 one; bicyclo compound; dioxane derivative; formaldehyde; manganese dioxide; pyridine derivative; sulfuric acid; unclassified drug; article; catalysis; conformation; polymerization; reaction analysis; synthesis; X ray diffraction
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/324/