Donor-acceptor origin of fullerene C60 dimerization

The fullerene dimerization is considered as a consequence of donor-acceptor interaction between monomer molecules which is significant for C 60+C60 binary system. The dimerization is provided by a two-well structure of the ground state energy term. Analyzing characteristics of the term, proven by quantum-chemical calculations at different starting intermolecular distances, mechanisms of both physically (photoexcitation, thermal, high pressure, plasma, electron beam, and electric field) and chemically (alkali-metal adducts AC60) stimulated dimerization processes are suggested. &copy ;2007 Wiley Periodicals. Inc.

Авторы
Издательство
John Wiley and Sons Inc.
Номер выпуска
13
Язык
Английский
Страницы
2361-2371
Статус
Опубликовано
Том
107
Год
2007
Организации
  • 1 Peoples' Friendship University of the Russian Federation, Scientific Research Department, 117198 Moscow, Russian Federation
Ключевые слова
Donor-acceptor interaction; Fullerene dimerization; Fullerenes C60 and alkali C60; Reaction barrier; Static electric field effect
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/3184/