Reactions of 9,10-phenanthrenequinone and its nitro derivatives with acetone in the presence of Al2O3

The addition of acetone to 9,10-phenanthrenequinone and 2-nitro-, 2,7-dinitro-, and 2,4,7-trinitro-9,10-phenatithrenequinones in the presence of Al2O3 affords mono- and bisadducts. The crystal structures of 10-hydroxy-10-(2-oxopropyl)-2-nitro-9,10-dihydrophenanthren-9-one and 9,10″:10,9″-bishemiketal of 9,10-dihydroxy-2-nitro-9,10-bis(2-oxopropyl)-9,10-dihydrophenanthrene were determined.

Авторы
Linko R.V. 1 , Belsky V.K.2 , Varlamov A.V. 1 , Zaitsev B.E. 1 , Chernyshev A.I. 1
Редакторы
-
Издательство
-
Номер выпуска
9
Язык
Английский
Страницы
1625-1629
Статус
Опубликовано
Подразделение
-
Номер
-
Том
50
Год
2001
Организации
  • 1 Russ. Univ. of People's Friendship, 6 ul. Miklukho-Maklaya, 117198 Moscow, Russian Federation
  • 2 Stt. Res. Ctr. of the Russ. Fed., L. Ya. Karpov Res. P., 10 ul. Vorontsovo Pole, 103064 Moscow, Russian Federation
Ключевые слова
(9,10-dihydroxy)nitro-9,10-bis(2-oxopropyl)-9,10-dihydrophenanthrenes, 9,10″:10,9″-bishemiketals; 9,10-phenanthrenequinone; Acetone; Alumina; nitro-9,10-phenanthrenequinones, 10-hydroxy10-(2-oxopropyl)-9,10-dihydrophenanthren-9-ones
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/285/