Synthesis and the crystal and molecular structures of (H3 L • Cl)[CoCl4] and H2 L[CuBr4] (L is 2,4,6-Tri(N,N-dimethylamino)methylphenol)

The complex compounds (H3 L • Cl)[CoCl4] (I) and H2 L[CuBr4] (II), where L is 2,4,6-tri(N,N-dimethylamino) methylphenol, were isolated in the crystalline state and studied by X-ray diffraction. The organic cations were found to be outer-sphere ligands. All three nitrogen atoms of the tertiary amino groups are protonated. In compound I, the H3 L 3+ cation exists as the cis tautomer. In compound II, the H2 L 2+ dication exists as the trans isomer. In the crystal structure, the dications are arranged in layers via hydrogen bonds. © 2010 Pleiades Publishing, Ltd.

Редакторы
-
Издательство
-
Номер выпуска
3
Язык
Английский
Страницы
428-431
Статус
Опубликовано
Подразделение
-
Номер
-
Том
55
Год
2010
Организации
  • 1 Peoples' Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
  • 2 Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow 105064, Russian Federation
Ключевые слова
Amino group; Complex compounds; Compound I; Crystal and molecular structure; Crystalline state; Dications; Nitrogen atom; Organic cations; Protonated; Trans isomers; Crystal structure; Crystalline materials; Hydrogen bonds; Positive ions; Spheres; X ray diffraction; Complexation
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2784/