Fluctuation model of operating mechanism of inhibiting layer: Dynamical structure of layer

A theoretical model of the stable operation of an inhibiting layer on a metal in a corrosive electrolyte is given. The model takes into account the energetic heterogeneity of the surface, which causes fluctuations in the concentration of ionic electrolyte components. The role of fluctuations in the structure of the layer, in which metal ions are involved, is determined. The structure is shown to be dynamic and characterized by certain porosity. © 2011 Pleiades Publishing, Ltd.

Авторы
Издательство
Maik Nauka Publishing / Springer SBM
Номер выпуска
1
Язык
Английский
Страницы
8-12
Статус
Опубликовано
Том
47
Год
2011
Организации
  • 1 Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow 105064, Russian Federation
  • 2 Russian Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Ключевые слова
Corrosive electrolytes; Dynamical structure; Energetic heterogeneity; Fluctuation model; Inhibiting layers; Ionic electrolytes; Operating mechanism; Stable operation; Theoretical models; Metal ions; Electrolytes
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2610/
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