9-[(2-Hydroxybenzylidene)amino]-11-(2-hydroxyphenyl)-10, 13-diphenyl-8-oxa-12-azoniatricyclo[7.3.1.02,7]trideca-2(7),3,5- triene acetate ethanol disolvate

The title compound, C36H31N2O 3+,C2H3O2 -·2C2H5OH, the product of a domino condensation of dibenzyl ketone with salicylic aldehyde and ammonium acetate, crystallized as the ethanol disolvate. The cation of the salt comprises a fused tricyclic system containing three six-membered rings (piperidine, dihydro-2H-pyran and benzene). The piperidine ring has the usual chair conformation, while the dihydropyran ring adopts a slightly distorted sofa conformation. In the crystal, there are six (one intra- and five intermolecular) independent hydrogen-bonding interactions: the intermolecular hydrogen bonds link the cations and anions and ethanol solvent molecules into ribbons along [001]. The ribbons are stacked along the a axis.

Авторы
Anh L.T.1 , Hieu T.H. 2 , Soldatenkov A.T. 2 , Soldatova S.A. 2 , Khrustalev V.N.3
Редакторы
-
Издательство
-
Номер выпуска
3
Язык
Английский
Страницы
o560-o561
Статус
Опубликовано
Подразделение
-
Номер
-
Том
67
Год
2011
Организации
  • 1 Department of Chemistry, Vietnam National University, 144 Xuan Thuy, Cau Giay, Hanoi, Viet Nam
  • 2 Organic Chemistry Department, Russian Peoples Friendship University, Miklukho-Maklaya St 6, Moscow 117198, Russian Federation
  • 3 X-Ray Structural Centre, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St, B-334, Moscow 119991, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2586/