Molecular wheel to monocyclic ring transition in boron-carbon mixed clusters C2B6 ̄ and C3B 5 ̄

In this joint experimental and theoretical work we present a novel type of structural transition occurring in the series of CxB 8-x ̄ (x = 1-8) mixed clusters upon increase of the carbon content from x = 2 to x = 3. The wheel to ring transition is surprising because it is rather planar-to-linear type of transition to be expected in the series since B8, B8 ̄, B8 2- and CB7 ̄ are known to possess wheel-type global minimum structures while C8 is linear. © 2011 the Owner Societies.

Авторы
Galeev T.R. 1 , Ivanov A.S. 2 , Romanescu C.3 , Li W.-L.3 , Bozhenko K.V. 2 , Wang L.-S.3 , Boldyrev A.I.1
Редакторы
-
Издательство
-
Номер выпуска
19
Язык
Английский
Страницы
8805-8810
Статус
Опубликовано
Подразделение
-
Номер
-
Том
13
Год
2011
Организации
  • 1 Department of Chemistry and Biochemistry, Utah State University, Old Main Hill 0300, Logan UT 84322-0300, United States
  • 2 Department of Physical and Colloid Chemistry, Peoples' Friendship University of Russia, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation
  • 3 Department of Chemistry, Brown University, 324 Brook Street Providence, Rhode PE 02912, United States
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2554/