Rac-(1S*,4aS*,8aS*)-4a-Hydroxy-2- methylperhydrospiro[isoquinoline-4,1′-cyclohexan]-2′-one

In the title compound, C15H25NO2, all three six-membered rings adopt chair conformations. The cyclohexane and piperidine rings within the perhydroisoquinoline are trans-trans fused. The N atom has a trigonal-pyramidal geometry (the sum of the bond angles is 328.0°). The methyl substituent occupies the sterically preferrable equatorial position. In the crystal, molecules form infinite [100] chains via O - H⋯N hydrogen bonds.

Авторы
Siaka S.1 , Soldatenkov A.T. 2 , Malkova A.V. 2 , Soldatova S.A. 2 , Khrustalev V.N.3
Редакторы
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Издательство
-
Номер выпуска
5
Язык
Английский
Страницы
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Статус
Опубликовано
Подразделение
-
Номер
-
Том
69
Год
2013
Организации
  • 1 Institut National Polytechnique Félix Houphouët-Boigny, Enseignant-Chercheur À l'Inp-HB de Yamoussoukro, BP 991, Yamoussoukro, Cote d'Ivoire
  • 2 Organic Chemistry Department, Russian Peoples Friendship University, Miklukho-Maklaya St. 6, Moscow 117198, Russian Federation
  • 3 X-Ray Structural Centre, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, B-334, Moscow 119991, Russian Federation
Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/2084/