Synthesis of pyrrolo[1,2-a][1,6]benzodiazonines from pyrrolo[1,2-a][1,4] benzodiazepines and alkynes containing electron-acceptor substituents

It has been established that the reaction of pyrrolo[1,2-a][1,4] benzodiazepines with activated alkynes gives pyrrolo[1,2-a][1,6]benzodiazonines as the products of diazepine ring expansion. In the case of pyrrolo[1,2-a][1,4] benzodiazepine, substituted with formyl group at the pyrrole ring, both expansion and cleavage of the diazepine fragment can occur. © 2013 Springer Science+Business Media New York.

Авторы
Voskressensky L.G. 1 , Borisova T.N. 1 , Babakhanova M.I. 1 , Chervyakova T.M. 1 , Titov A.A. 1 , Butin A.V.2, 3 , Nevolina T.A.2, 3 , Khrustalev V.N.4 , Varlamov A.V. 1
Редакторы
-
Издательство
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Номер выпуска
7
Язык
Английский
Страницы
1024-1032
Статус
Опубликовано
Подразделение
-
Номер
-
Том
49
Год
2013
Организации
  • 1 Peoples' Friendship University of Russia, 6 Miklukho-Maklaya St., Moscow 117198, Russian Federation
  • 2 Research Institute for Heterocyclic Compounds, Kuban State University of Technology, 2 Moscow St., Krasnodar 350072, Russian Federation
  • 3 Perm State National Research University, 15 Bukirev St., Perm 614990, Russian Federation
  • 4 A. N. Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, 28 Vavilov St., Moscow 119991, Russian Federation
Ключевые слова
activated alkynes; diazepine ring expansion; diazepine ring opening; pyrrolo[1,2-a][1,4]benzodiazepines; pyrrolo[1,2-a][1,6]benzodiazonines
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/1986/