1-(3,3-Dimethyl-3,4-dihydroisoquinoline-1-yl)-1-(quinoline-2-yl)-methane: Structure and peculiarities of its complexation with metal salts

1-(3,3-Dimethyl-3,4-dihydroisoquinoline-1-yl)-1-(quinoline-2-yl)methane (I) is studied using X-ray diffraction analysis. Molecule I is shown to have a flattened structure and to exist in the enamine tautomeric form: the active hydrogen atom is at the N(1) atom of the dihydroisoquinoline fragment. Molecule I is stabilized by the N-H⋯N intramolecular hydrogen bond.

Авторы
Sokol V.I.1 , Davydov V.V. 2 , Elekhina N.A. 2 , Shklyaev Yu.V.3 , Sergienko V.S.1
Редакторы
-
Издательство
-
Номер выпуска
6
Язык
Английский
Страницы
439-449
Статус
Опубликовано
Подразделение
-
Номер
-
Том
28
Год
2002
Организации
  • 1 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russian Federation
  • 2 University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russian Federation
Ключевые слова
1 (3,3 dimethyl 3,4 dihydroisoquinolin 1 yl) 1 (quinolin 2 yl)methane; quinoline derivative; unclassified drug; article; chemical structure; complex formation; hydrogen bond; molecular stability; structure analysis; temperature dependence; X ray diffraction
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/197/