Transformation of furfural into dimorpholinocyclopentenone using Al-SBA-15 materials

Dimorpholinocyclopentenone, being a relevant chemical compound widespread employed in the pharmaceutical industry, can be synthesized by a facile chemically catalyzed conversion reaction between furfural and morpholine. This reaction was investigated in this work by employing a simple, affordable non-noble metal mesoporous Al-SBA-15 with improved catalytic activity and superior product selectivity. The prepared materials shown a mesoporous structure with high pore volume and enlarged surface area, which are impacted by the quantity of aluminium atom incorporated. These differences leading to superior catalytic properties of Al-SBA-15 with a Si/Al ratio of 10.

Авторы
Lopez Fernandez Miriam , Len Thomas , Urbano Juan , Balu Alina , Luque Rafael 3, 4, 5
Издательство
Elsevier Science Publishing Company, Inc.
Язык
Английский
Страницы
101573
Статус
Опубликовано
Том
39
Год
2024
Организации
  • 1 Departamento de Química Orgánica, Instituto de Química Fina y Nanoquímica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba, E14014, Spain
  • 2 Laboratory of Sustainable and Circular Technology. CIDERTA and Chemistry Department, Faculty of Experimental Sciences. Campus de ‘El Carmen’, University of Huelva, 21071, Huelva, Spain
  • 3 National University of Science and Technology Polytehnica Bucharest, 1-7 Gheorghe Polizu Str., Bucharest, Romania
  • 4 Universidad ECOTEC, Km. 13.5 Samborondón, Samborondón, EC092302, Ecuador
  • 5 Российский университет дружбы народов им. Патриса Лумумбы
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