Geochemical characteristics of Neoproterozoic metavolcanic rocks of Ariab Auriferous Volcanogenic Massive Sulfide deposit, Red Sea hills, North-East Sudan

The Ariab volcanogenic massive sulfide (VMS, ∼118.3 Mt with >2 Moz Au recovered) district is part of the Ariab-Arbaat belt located in the Haya terrane, Red Sea Hills, Northeast Sudan. The gold-bearing gossan and VMS deposits are mainly hosted by Neoproterozoic bimodal volcanic succession. The petrogenesis, age dating, metallogenic evolution, and tectonic environment as well as the relationship between the metals occurrences and hosting materials remain poorly constrained and controversial. The study aims to investigate the geochemical characteristics of metavolcanic rocks of Ariab Auriferous Volcanogenic Massive Sulfide. XRF and ICP-MS techniques were employed to analyze major, trace, and rare earth elements content. The metavolcanics composition of Ariab VMS hosting rocks ranging from basalt to rhyolitic lava with variable pyroclastics. The chemical affinity varies from sub-alkaline tholeiitic to calc-alkaline nature, raising an argument against the possibility of fractional crystallization. The Ariab VMS metavolcanics were likely formed in the intra-oceanic arc tectonic environment. Ariab mafic lava is characterized notably by high Cr and Ni concentrations. The negative and positive anomalies in trace element profiles are typically ocean island basalt patterns, implying minimal crustal contamination. The geochemical results of dacitic and rhyolitic rocks reveal an assimilation-fractional-crystallization process, including the possibility that plagioclase-rich restite was formed in the parent magma source with a significant contribution from the old crust. The mobility of elements such as Zn, Cu, Pb, Ag, Au, As, and Co complicates the determination of their primary abundances. The partitioning behavior of REEs, the geochemical signatures of chalcophile elements, and their associations with VMS deposits, underscores the complex interaction between igneous processes and subsequent hydrothermal alteration. © 2024 Elsevier Ltd