Crystal structure and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromophenyl)-1,2,3,4- tetrahydroquinolin-4-yl]pyrrolidin-2-one

This study presents the synthesis, characterization and Hirshfeld surface analysis of 1-[6-bromo-2-(3-bromophenyl)-1,2,3,4-tetrahydroquinolin-4-yl]pyrrolidin-2- one, C19H18Br2N2O. In the title compound, the pyrrolidine ring adopts a distorted envelope configuration. In the crystal, molecules are linked by intermolecular N-H O, C-H O and C-H Br hydrogen bonds, forming a three-dimensional network. In addition, pairs of molecules along the c axis are connected by C-H π interactions. According to a Hirshfeld surface study, H H (36.9%), Br H/ Br (28.2%) and C H/H C (24.3%) interactions are the most significant contributors to the crystal packing. © 2024 International Union of Crystallography. All rights reserved.

Авторы
Pronina A.A. , Kutasevich A.G. , Grigoriev M.S. , Hasanov K.I. , Sadikhova N.D. , Javadzade T.A. , Akkurt M. , Bhattarai A.
Издательство
International Union of Crystallography
Номер выпуска
Pt 9
Язык
Английский
Страницы
967-972
Статус
Опубликовано
Том
80
Год
2024
Организации
  • 1 RUDN University, 6 Miklukho-Maklaya St, Moscow, 117198, Russian Federation
  • 2 Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskiy prospect 31-4, Moscow, 119071, Russian Federation
  • 3 Western Caspian University, Istiqlaliyyat Street 31, Baku, AZ1001, Azerbaijan
  • 4 Azerbaijan Medical University, Scientific Research Centre (SRC), A. Kasumzade St. 14., Baku, AZ 1022, Azerbaijan
  • 5 Department of Chemistry, Baku State University, Z. Xalilov Str. 23, Baku, Az 1148, Azerbaijan
  • 6 Department of Chemistry and Chemical Engineering, Khazar University, Mahsati St. 41, Baku, AZ 1096, Azerbaijan
  • 7 Department of Physics, Faculty of Sciences, Erciyes University, Kayseri, 38039, Turkey
  • 8 Department of Chemistry, M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal
Ключевые слова
crystal structure; Hirshfeld surface analysis; hydrogen bonds; tetrahydroquinoline; the Povarov method
Цитировать
Поделиться

Другие записи