Crystal structure and Hirshfeld surface analysis of 4-cyano-N-[(4-cyano­phen­yl)sulfon­yl]-N-[2-(5-methyl­furan-2-yl)phen­yl]benzene­sulfonamide

In the title compound, C25H17N3O5S2, intra­molecular π-π inter­actions [centroid-to-centroid distance = 3.5640 (9) Å] are observed between the furan and benzene rings of the 4-cyano­phenyl group. In the crystal, mol­ecules are connected via C - H⋯O and C - H⋯N hydrogen bonds, forming layers parallel to the (100) plane. These layers are inter­connected by C - H⋯π inter­actions and weak van der Waals inter­actions. Hirshfeld surface analysis indicates that H⋯H (30.2%), N⋯H/H⋯N (22.3%), C⋯H/H⋯C (17.9%) and O⋯H/H⋯O (15.4%) inter­actions make the most significant contributions to the crystal packing. © 2023 International Union of Crystallography. All rights reserved.

Авторы
Mammadova G.Z. , Yakovleva E.D. , Burkin G.M. , Khrustalev V.N. , Akkurt M. , Çelikesir S.T. , Bhattarai A.
Издательство
International Union of Crystallography
Язык
Английский
Страницы
747-751
Статус
Опубликовано
Том
79
Год
2023
Организации
  • 1 Organic Chemistry Department, Baku State University, Z. Xalilov Str. 23, Baku, Az 1148, Azerbaijan
  • 2 Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 3 Zelinsky Institute of Organic Chemistry of RAS, 4, 7 Leninsky Prospect, Moscow, 119991, Russian Federation
  • 4 Department of Physics, Faculty of Sciences, Erciyes University, Kayseri, 38039, Turkey
  • 5 Department of Chemistry, M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal
Ключевые слова
C - H⋯π inter­actions; crystal structure; Hirshfeld surface analysis; hydrogen bonds; sulfonamides; π-π inter­actions
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