OD ESR signals of excess electrons in liquid hydrocarbons depending on the geminate recombination parameters, theory and experiment

The intensity of optically detected ESR (OD ESR) signals from radical-ion pairs in solution under ionizing irradiation has been investigated experimentally and theoretically as a function of the microwave power, the geminate recombination parameters, the diffusion coefficient, the distance distribution function of pairs, and the spin-lattice relaxation time. In line with theoritical predictions, the temperature dependence of an OD ESR signal has been shown to have a maximum depending on the microwave power. The experimental dependence has been measured for the system e- + triethylamine+ (TEA) in 3-methylpentane. Agreement between the theoretical and experimental dependences is discussed. © 1985.

Авторы
Smirnov S.N.1 , Rogov V.A.1 , Shustov A.S. 2 , Sheberstov S.V. 2 , Panfilovitch N.V. 2 , Anisimov O.A.3 , Molin Yu.N.3
Редакторы
-
Журнал
Издательство
-
Номер выпуска
2-3
Язык
Английский
Страницы
381-387
Статус
Опубликовано
Подразделение
-
Номер
-
Том
92
Год
1985
Организации
  • 1 Institute of Catalysis, Novosibirsk, 630090, Russian Federation
  • 2 Peoples Friendship University, Moscow, Russian Federation
  • 3 Institute of Chemical Kinetics and Combustion, Novosibirsk, 630090, Russian Federation
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/1366/