Adducts of tin(II) chloride with imidazole and methylimidazoles

Reactions of SnCl2 with excess imidazole, 1- methyl-, 4-methyl- and 1,2-dimethylimidazole in THF afforded solid 1:2 adducts in each case. The products were air-sensitive white solids with minimal solubilities in most unreactive solvents. Investigation of the adducts by IR, NMR and X-ray PES indicated that their structures involved coordination of the pyridine-like nitrogen atom of the imidazole ring to the tin atom. Proton and ligand exchange reactions were indicated in DMSO solutions of the adducts. © 1989.

Авторы
Vasnin S. 1 , Geanangel R.A.2
Редакторы
-
Издательство
-
Номер выпуска
2
Язык
Английский
Страницы
167-170
Статус
Опубликовано
Подразделение
-
Номер
-
Том
160
Год
1989
Организации
  • 1 Patrice Lamumba People's Friendship University, Moscow, Russian Federation
  • 2 Department of Chemistry, University of Houston, Houston, TX, United States
Ключевые слова
-
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/1194/