Synthesis and Structure of Metal Complexes of 1-(1-R-3-Methylpyrazole-5- onilidene-4)-1,2,3,4-tetrahydroisoquinoline Derivatives

Twenty new complexes were synthesized by reacting Co(II), Cu(II), Zn, Cr(III), Fe(III), Cd and Ag salts with 3,3-dimethyl-1-(3-methylpyrazole-5- onilidene-4)-1,2,3,4-tetrahydroisoquinoline (L1), spiro{cyclohexane-1,3′-[1-(1-phenyl-3-methylpyrazole-5-onilidene-4)-1,2,3, 4-tetrahydroisoquinoline]} (L2), and 3,3-dimethyl-1-(1-phenyl-3- methylpyrazole-5-onilidene-4)-1,2,3,4-tetrahydroisoquinoline (L3). These compounds were studied by IR and electronic absorption spectroscopy. The type of coordination of their ligands was discussed on the basis of the results obtained and X-ray diffraction data for L3 and [CuL2 2Cl2]·2L2 obtained previously.

Авторы
Davydov V.V. 1 , Al-Salekh O.A. 1 , Mercur'eva N.Yu. 1 , Ryabov M.A. 1 , Sokol V.I.2 , Sergienko V.S.2 , Shklyaev Yu.V.3
Редакторы
-
Издательство
-
Номер выпуска
1
Язык
Английский
Страницы
16-21
Статус
Опубликовано
Подразделение
-
Номер
-
Том
29
Год
2003
Организации
  • 1 University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 2 Kurnakov Inst. Gen. and Inorg. Chem., Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russian Federation
  • 3 Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, Perm, Russian Federation
Ключевые слова
3,3 dimethyl 1 (1 phenyl 3 methylpyrazol 5 onilidene 4) 1,2,3,4 tetrahydroisoquinoline; 3,3 dimethyl 1 (3 methylpyrazol 5 onilidene 4) 1,2,3,4 tetrahydroisoquinoline; ligand; metal derivative; spiro[cyclohexane 1,3' [1 (1 phenyl 3 methylpyrazol 5 onilidene 4) 1,2,3,4 tetrahydrosoquinoline]]; tetrahydroisoquinoline derivative; unclassified drug; absorption spectroscopy; article; complex formation; drug structure; drug synthesis; infrared spectroscopy; structure analysis; X ray diffraction
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/117/