Synthesis and crystal structure of the calcium chloride complex with ε-caprolactam

The compound of the CaCl2·2CL·H2O composition, where CL is ε-caprolactam, has been prepared and studied by X-ray crystallography. The crystals are monoclinic, space group P2 1/n, unit cell parameters a = 6.042(3) Å, b = 6.086(3) Å, c = 26.105(10) Å, β= 94.62(4)°, V = 956.8(7) Å3, Z = 2. The structure of the compound is molecular. The molecular packing is stack-layered; the layers are perpendicular to the z. axis. Each ε-caprolactam molecule has its standard chair conformation. Both ε-caprolactam molecules are coordinated to the Ca atom through the carbonyl oxygen atom.

Авторы
Khrustalev V.A.1 , Vanina G.E. 2 , Venskovskii N.U. 2 , Lobanov N.N. 2 , Antipin M.Yu.1 , Molodkin A.K. 2 , Ezhov A.I. 2
Редакторы
-
Издательство
IAPC Nauka/Interperiodica
Номер выпуска
7
Язык
Английский
Страницы
1020-1023
Статус
Опубликовано
Подразделение
-
DOI
-
Номер
-
Том
48
Год
2003
Организации
  • 1 Nesmeyanov Inst. Organoelement C., Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russian Federation
  • 2 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
Ключевые слова
calcium chloride; caprolactam; article; chemical reaction; complex formation; crystal structure; reaction analysis; structure analysis; synthesis; X ray crystallography
Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/105/