Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties

New dinuclear silver(I) and copper(I) 3,5-bis(trifluoromethyl)pyrazolate compounds were prepared by the reaction of the corresponding trinuclear metal complexes with tertiary phosphines (PPh3, PCy3). In the case of copper(I) trinuclear pyrazolate it was shown that the product structure depends on the reagent ratio: mono- and dinuclear complexes were obtained. All the dinuclear complexes obtained exhibit light emission in the solid state under UV irradiation. The observed photoluminescence behavior was confirmed by the TD-DFT study. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Авторы
Titov A.A. 1 , Filippov O.A. 1 , Smol'yakov A.F. 1, 2 , Baranova K.F.1, 3 , Titova E.M. 1, 2 , Averin A.A.4 , Shubina E.S. 1
Журнал
European Journal of Inorganic Chemistry
Издательство
Wiley-VCH Verlag
Язык
Английский
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1002/ejic.201801318
Год
2019
Организации
  • 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov st. 28, Moscow, 119991, Russian Federation
  • 2 Inorganic Chemistry Department, Peoples' Friendship University of Russia, Miklukho-Maklaya str. 6, Moscow, 117198, Russian Federation
  • 3 Faculty of Chemistry, Lomonosov Moscow State University, 1-3 Leninskie Gory, Moscow, 119991, Russian Federation
  • 4 A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prospect 31, Moscow, 119071, Russian Federation
Ключевые слова
Copper; Luminescence; N ligands; Phosphines; Silver; Structure elucidation
Дата создания
04.02.2019
Дата изменения
04.02.2019
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/36153/
Поделиться

Другие записи