Springer Geography.
Springer.
2019.
P. 106-111
Dinuclear CuI and AgI Pyrazolates Supported with Tertiary Phosphines: Synthesis, Structures, and Photophysical Properties
New dinuclear silver(I) and copper(I) 3,5-bis(trifluoromethyl)pyrazolate compounds were prepared by the reaction of the corresponding trinuclear metal complexes with tertiary phosphines (PPh3, PCy3). In the case of copper(I) trinuclear pyrazolate it was shown that the product structure depends on the reagent ratio: mono- and dinuclear complexes were obtained. All the dinuclear complexes obtained exhibit light emission in the solid state under UV irradiation. The observed photoluminescence behavior was confirmed by the TD-DFT study. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Authors
Titov A.A.
1
,
Filippov O.A.
1
,
Smol'yakov A.F.
1,
2
,
Baranova K.F.1,
3
,
Titova E.M.
1,
2
,
Averin A.A.4
,
Shubina E.S.
1
Publisher
Wiley-VCH Verlag
Language
English
Status
Published
Link
Year
2019
Organizations
- 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov st. 28, Moscow, 119991, Russian Federation
- 2 Inorganic Chemistry Department, Peoples' Friendship University of Russia, Miklukho-Maklaya str. 6, Moscow, 117198, Russian Federation
- 3 Faculty of Chemistry, Lomonosov Moscow State University, 1-3 Leninskie Gory, Moscow, 119991, Russian Federation
- 4 A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prospect 31, Moscow, 119071, Russian Federation
Keywords
Copper; Luminescence; N ligands; Phosphines; Silver; Structure elucidation
Date of creation
04.02.2019
Date of change
04.02.2019
Share
Other records
SUITMA 9: URBANIZATION AS A CHALLENGE AND AN OPPORTUNITY FOR SOILS FUNCTIONS AND ECOSYSTEM SERVICES
Article
Springer Geography.
Springer.
2019.
P. 1-3