Gold(I) Complex [(Phen)2H][Au(SCN)2]: Synthesis and Properties

[(Phen)2H]Au(SCN)2] complex was synthesized from aqueous solutions of auric chloride acid, potassium thiocyanate, and an acetone solution of 1,10-phenanthroline. The oxidation number +1 for gold is evidenced by X-ray photoelectron spectroscopy and by the synthesis of the complex with preliminary reduction of Au(III) to Au(I) by means of sodium sulfite. The presence of [(Phen)2H]+ and thiocyanate groups coordinated to gold through sulfur atoms is confirmed by IR spectroscopy.

Editors
-
Publisher
IAPC Nauka/Interperiodica
Number of issue
7
Language
English
Pages
1102-1103
Status
Published
Department
-
DOI
-
Number
-
Volume
41
Year
1996
Organizations
  • 1 University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Keywords
-
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/851/