Advances in catalytic decarboxylation of bioderived fatty acids to diesel-range alkanes

Biodiesel is an important alternative fuel as far as sustainability and environmental issues are concerned. The decarboxylation of bioderived fatty acids is receiving great attention for green diesel production, with resulting C1-shortened alkanes among the diesel-range alkanes typically existing in petroleum diesel. Alkane-containing green diesel possesses significant advantages including high caloric value, irreversibility of the production reaction and the existence in liquid form up to C17 alkanes. The decarboxylation approach has a significant potential in taking a central role in transformation of bioderived fatty acids into green diesel. In the present review, it aims at discussing the progress on both chemo- and bio-catalytic decarboxylation reactions and the pros and cons of their application for green fuel synthesis. Particularly, the mild biocatalytic decarboxylation reactions so far have not been included in reviews focusing on green diesel production. © 2022 Elsevier Ltd

Authors
Chen B.-S.1 , Zeng Y.-Y.1 , Liu L. 1, 2 , Chen L.3 , Duan P.3 , Luque R. 4, 5 , Ge R.6, 7 , Zhang W.6, 7
Publisher
Elsevier Ltd
Language
English
Status
Published
Number
112178
Volume
158
Year
2022
Organizations
  • 1 School of Marine Sciences, Sun Yat-Sen University, Zhuhai, 519080, China
  • 2 Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai, 519080, China
  • 3 School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, China
  • 4 Departamento de Quimica Organica, University of Cordoba, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba, E14014, Spain
  • 5 Peoples Friendship University of Russia (RUDN University), 6 Miklukho Maklaya str., Moscow, 117198, Russian Federation
  • 6 Tianjin Institute of Industrial Biotechnology, Chinese Academy of Sciences, 32 West 7th Avenue, Tianjin, 300308, China
  • 7 National Technology Innovation Center of Synthetic Biology, 32 West 7th Avenue, Tianjin, 300308, China
Keywords
Chemocatalysis; Decarboxylation; Enzymes; Green diesel; Renewable sources; Sustainability
Date of creation
06.07.2022
Date of change
06.07.2022
Short link
https://repository.rudn.ru/en/records/article/record/83739/
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