Molecular Catalysis. Vol. 522. 2022.
Methacrylate-Containing Phosphazene Oligomers
Abstract: Methacrylate-containing phosphazene oligomers are synthesized by the reaction of phosphazene-containing epoxy compounds with methacrylic acid and characterized by 1Н and 31Р NMR spectroscopy, MALDI-TOF mass spectrometry, and functional analysis. Methacrylate-containing phosphazene oligomers with the addition of 0.5% hydroquinone are stable under storage at normal temperature for 2 to 3 weeks but are easily involved in benzoyl peroxide-initiated copolymerization with methyl acrylate to give rise to copolymers with the quantitative content of the gel fraction. © 2022, Pleiades Publishing, Ltd.
Authors
Sirotin I.S. 1 , Son V.X. 1 , Bilichenko Y.V. 1 , Borisov R.S. 1, 2, 3 , Gorbunova E.A. 1 , Kireev V.V. 1
Journal
Publisher
Pleiades Publishing
Issue number
2
Language
English
Pages
109-116
State
Published
Link
Volume
64
Year
2022
Organizations
- 1 Mendeleev University of Chemical Technology, Moscow, 125047, Russian Federation
- 2 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russian Federation
- 3 Peoples’ Friendship University of Russia, Moscow, 117198, Russian Federation
Keywords
Benzoyl peroxide; Mass spectrometry; Nuclear magnetic resonance spectroscopy; Copolymerisation; Epoxy compound; Gel fraction; MALDI-TOF mass spectrometry; Methacrylic acids; Methyl acrylates; NMR-spectroscopy; Phosphazenes; Synthesised; Oligomers
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Molecular Catalysis. Vol. 522. 2022.