Novel carbonate/pyridine tetranuclear nickel complex, exhibiting slow relaxation of the magnetization

Tetranuclear [Ni4(CO3)4(pyridine)8·Na]Cl·pyridine·H2O compound with unusual square-planar geometry was obtained via spontaneous fixation of atmospheric CO2 and its conversion into carbonate bridging ligands. This compound exhibits a slow relaxation of the magnetization caused by a spin-glass behaviour. © 2021 Elsevier B.V.

Authors
Kulakova A.N. 1, 2, 3 , Bilyachenko A.N. 1, 3 , Korlyukov A.A. 1, 4 , Levitsky M.M. 1 , Long J. 2 , Guari Y. 2 , Larionova J. 2
Journal
Journal of Organometallic Chemistry
Language
English
Status
Published
Link
External link
DOI
10.1016/j.jorganchem.2021.121815
Number
121815
Volume
942
Year
2021
Organizations
  • 1 Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilov Str.Moscow 119334, Russian Federation
  • 2 Institut Charles Gerhardt, Equipe Ingénierie Moléculaire et Nano-Objets, Univ. Montpellier, CNRS, ENSCM, Place Eugène Bataillon, Montpellier Cedex 5, 34095, France
  • 3 Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklaya, Str., 6, Moscow, 117198, Russian Federation
  • 4 Pirogov Russian National Research Medical University, Ostrovitianov Str., 1, Moscow, 117997, Russian Federation
Keywords
Nickel complexes; Spin-glass behaviour; X-ray
Date of creation
20.07.2021
Date of change
20.07.2021
Short link
https://repository.rudn.ru/en/records/article/record/74199/
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