Enantiomerically enriched 1,2-P,N-bidentate ferrocenyl ligands for 1,3-dipolar cycloaddition and transfer hydrogenation reactions

Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl2(PPh3)3] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones. © 2018 by the authors.

Authors
Utepova I.A. 1, 2 , Serebrennikova P.O. 1 , Streltsova M.S. 1 , Musikhina A.A. 1 , Fedorchenko T.G. 2 , Chupakhin O.N. 1, 2 , Antonchick A.P. 3, 4, 5
Journal
Molecules
Publisher
MDPI AG
Issue number
6
Language
English
State
Published
Link
External link
DOI
10.3390/MOLECULES23061311
Number
1311
Volume
23
Year
2018
Organizations
  • 1 Ural Federal University, 19 Mira Street, Ekaterinburg, 620002, Russian Federation
  • 2 Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Street, Ekaterinburg, 620041, Russian Federation
  • 3 Chemische Biologie, Max-Planck-Institut f r Molekulare Physiologie, Otto-Hahn Strasse 11, Dortmund, 44227, Germany
  • 4 Fakult t Chemie und Chemische Biologie, Technische Universit t Dortmund, Otto-Hahn-Strasse 4a, Dortmund, 44227, Germany
  • 5 Faculty of Science, Peoples’ Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Germany
Keywords
Catalysis; Cycloaddition; Ferrocenyl ligands; Hydrogen transfer
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