Furan Oxidation Reactions in the Total Synthesis of Natural Products

Recent developments on the transformations of furans under oxidative conditions toward the total synthesis of complex natural compounds are discussed. Reactions and methods are classified according to the type of oxidant used. Comparisons are then made between all the strategies to provide a comprehensive overview. This review covers the most prominent work published from 2011 until 2017. 1 Introduction 2 Reagents and Methods for Oxidation of the Furan Ring 2.1 Singlet Oxygen 2.2 Peroxides and Hydroperoxides 2.3 Quinones 2.4 Halogen-Based Oxidants 2.5 Chromium-Based Oxidants 3 The Achmatowicz Reaction 3.1 Halogen-Based Oxidants 3.2 Hydroperoxides 3.3 Enzymatic Oxidation 4 Conclusion. © Georg Thieme Verlag Stuttgart. New York.

Authors
Makarov A.S.1 , Uchuskin M.G. 1 , Trushkov I.V. 2, 3
Journal
Synthesis
Number of issue
16
Language
English
Pages
3059-3086
Status
Published
Link
External link
DOI
10.1055/s-0037-1610021
Volume
50
Year
2018
Organizations
  • 1 Department of Chemistry, Perm State University, Bukireva 15, Perm, 614990, Russian Federation
  • 2 Dmitry Rogachev National Research Center of Pediatric Hematology, Oncology and Immunology, Samory Mashela 1, Moscow, 117997, Russian Federation
  • 3 Faculty of Science, Peoples' Friendship University of Russia, RUDN University, Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
Keywords
furans; natural products; oxidation; rearrangement; total synthesis
Date of creation
19.10.2018
Date of change
28.09.2021
Short link
https://repository.rudn.ru/en/records/article/record/7288/
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