Ruthenium-Catalyzed Reductive Amidation without an External Hydrogen Source

A catalytic reaction between aldehydes and primary amides that leads to N-alkylated amides was investigated. The developed protocol employs carbon monoxide as a deoxygenative agent and, therefore, avoids the use of an external hydrogen source. Cyclopentadienyl ruthenium complexes provided excellent catalytic efficiency and could be used with loadings as low as 0.5–1 mol-%. A representative number of secondary amides were successfully prepared in yields of 70–84 %. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Authors
Yagafarov N.Z. 1 , Muratov K.M.1 , Biriukov K.1 , Usanov D.L.2 , Chusova O. 3 , Perekalin D.S. 1 , Chusov D. 1, 3
Number of issue
4
Language
English
Pages
557-563
Status
Published
Volume
2018
Year
2018
Organizations
  • 1 Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova St. 28, Moscow, 119991, Russian Federation
  • 2 Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, United States
  • 3 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
Keywords
Aldehydes; Amides; Homogeneous catalysis; Reductive amidation; Ruthenium
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/6890/
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Russian Journal of Organic Chemistry. Vol. 54. 2018. P. 157-371