Journal of Organometallic Chemistry. Vol. 867. 2018. P.. 71-78
Indenyl rhodium complexes. Synthesis and catalytic activity in reductive amination using carbon monoxide as a reducing agent
Indenyl-ligated rhodium(III) catalyst [(η5-indenyl)RhX2]n (1) is reported for the synthesis of alkylated amines via catalytic reductive amination using carbon monoxide as a reducing agent. Water as a solvent was found to be the best media for the reaction. Complex 1 was synthesized via a high-yielding procedure based on the reaction of bis(ethylene) derivative (η5-indenyl)Rh(C2H4)2 with iodine. © 2017 Elsevier B.V.
Authors
Runikhina S.A. 1 , Arsenov M.A. 1 , Kharitonov V.B. 1 , Sovdagarova E.R. 1 , Chusova O. 2 , Nelyubina Y.V. 1 , Denisov G.L. 1 , Usanov D.L. 3 , Chusov D. 1, 2 , Loginov D.A. 1
Language
English
Pages
106-112
State
Published
Link
Volume
867
Year
2018
Organizations
- 1 A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, Moscow, 119991, Russian Federation
- 2 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
- 3 C/a: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, United States
Keywords
Amines; Carbon monoxide; Indenyl rhodium; Reductive amination; Water-gas shift reaction
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Other records
Journal of Organometallic Chemistry. Vol. 867. 2018. P.. 193-200