Indenyl rhodium complexes. Synthesis and catalytic activity in reductive amination using carbon monoxide as a reducing agent

Indenyl-ligated rhodium(III) catalyst [(η5-indenyl)RhX2]n (1) is reported for the synthesis of alkylated amines via catalytic reductive amination using carbon monoxide as a reducing agent. Water as a solvent was found to be the best media for the reaction. Complex 1 was synthesized via a high-yielding procedure based on the reaction of bis(ethylene) derivative (η5-indenyl)Rh(C2H4)2 with iodine. © 2017 Elsevier B.V.

Authors
Runikhina S.A.1 , Arsenov M.A.1 , Kharitonov V.B.1 , Sovdagarova E.R.1 , Chusova O. 2 , Nelyubina Y.V.1 , Denisov G.L.1 , Usanov D.L.3 , Chusov D. 1, 2 , Loginov D.A.1
Journal
Journal of Organometallic Chemistry
Language
English
Pages
106-112
Status
Published
Link
External link
DOI
10.1016/j.jorganchem.2017.11.003
Volume
867
Year
2018
Organizations
  • 1 A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, Moscow, 119991, Russian Federation
  • 2 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 3 C/a: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, United States
Keywords
Amines; Carbon monoxide; Indenyl rhodium; Reductive amination; Water-gas shift reaction
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/6526/
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