Journal of Organometallic Chemistry.
Vol. 867.
2018.
P. 71-78
Indenyl rhodium complexes. Synthesis and catalytic activity in reductive amination using carbon monoxide as a reducing agent
Indenyl-ligated rhodium(III) catalyst [(η5-indenyl)RhX2]n (1) is reported for the synthesis of alkylated amines via catalytic reductive amination using carbon monoxide as a reducing agent. Water as a solvent was found to be the best media for the reaction. Complex 1 was synthesized via a high-yielding procedure based on the reaction of bis(ethylene) derivative (η5-indenyl)Rh(C2H4)2 with iodine. © 2017 Elsevier B.V.
Authors
Runikhina S.A.1
,
Arsenov M.A.1
,
Kharitonov V.B.1
,
Sovdagarova E.R.1
,
Chusova O.
2
,
Nelyubina Y.V.1
,
Denisov G.L.1
,
Usanov D.L.3
,
Chusov D.
1,
2
,
Loginov D.A.1
Language
English
Pages
106-112
Status
Published
Link
Volume
867
Year
2018
Organizations
- 1 A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, Moscow, 119991, Russian Federation
- 2 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
- 3 C/a: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, United States
Keywords
Amines; Carbon monoxide; Indenyl rhodium; Reductive amination; Water-gas shift reaction
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Other records
Journal of Organometallic Chemistry.
Vol. 867.
2018.
P. 193-200