Effect of Composition on the Dielectric Properties of (1 – x)Ba(Ti0.75Sn0.25)O3 · xPbTiO3 Solid Solutions

Abstract—: (1 – x)Ba(Ti0.75Sn0.25)O3 ∙ xPbTiO3 (0 ≤ x ≤ 1) samples prepared by a standard ceramic processing route have been characterized by X-ray diffraction, thermogravimetry, and dielectric, piezoelectric, and pyroelectric measurements. The results demonstrate that the system in question contains solid solutions with the perovskite structure, which have cubic symmetry for x < 0.2 and tetragonal symmetry for x ≥ 0.2. Increasing the percentage of PbTiO3 in the samples has been shown to cause sequential changes in their dielectric properties in the following sequence: ferroelectric relaxor, reentrant ferroelectric relaxor, ferroelectric with a diffuse phase transition, and conventional ferroelectric. © 2020, Pleiades Publishing, Ltd.

Authors
Spitsin A.I.1 , Bush A.A. 1 , Kozlov V.I. 1 , Stepanov A.V.1 , Kamentsev K.E. 1 , Tishchenko E.A. 2, 3
Journal
Inorganic Materials
Number of issue
3
Language
English
Pages
297-303
Status
Published
Link
External link
DOI
10.1134/S0020168520020168
Volume
56
Year
2020
Organizations
  • 1 MIREA—Russian Technological University, pr. Vernadskogo 78, Moscow, 119454, Russian Federation
  • 2 Kapitza Institute for Physical Problems, Russian Academy of Sciences, ul. Kosygina 2, Moscow, 117339, Russian Federation
  • 3 Peoples’ Friendship University of Russia, ul. Ordzhonikidze 3, Moscow, 117198, Russian Federation
Keywords
dielectric properties; dielectric relaxation; ferroelectric ceramics; phase transitions; solid solutions; X-ray diffraction analysis
Date of creation
02.11.2020
Date of change
02.11.2020
Short link
https://repository.rudn.ru/en/records/article/record/64949/
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