ChemistrySelect.
Wiley-Blackwell.
Vol. 5.
2020.
P. 4601-4607
Unusual Transformations of Cyclic Allenes with an Enamine Moiety into Complex Frameworks
The thermolysis reactions of benzoazacyclodecatrienes under microwave irradiation conditions in toluene at 150 °C afforded complex azabenzo[ a ]cyclopropa[ cd ]azulene and (epiminomethano)cyclopenta[ a ]indene frameworks. Cyclopropanes were established as intermediates of the ultimate thermolysis products. © 2020 Georg Thieme Verlag. All rights reserved.
Authors
Titov A.A.
1
,
Kobzev M.S.
1
,
Borisova T.N.
1
,
Sorokina E.A.
1
,
Van Der Eycken E. ,
Varlamov A.V.
1
,
Voskressensky L.G.
1
Journal
Number of issue
7
Language
English
Pages
672-676
Status
Published
Link
Volume
31
Year
2020
Organizations
- 1 Organic Chemistry Department, Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St, Moscow, 117198, Russian Federation
- 2 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven (KU Leuven), Celestijnenlaan 200F, Leuven, 3001, Belgium
Keywords
azacyclic allene; cyclopropanes; epiminomethanocyclopentaindenes; microwave-assisted reaction; polyheterocyclic compounds; thermal transformation
Date of creation
02.11.2020
Date of change
02.11.2020
Share
Other records
Dalton Transactions.
Royal Society of Chemistry.
Vol. 49.
2020.
P. 4710-4724