Cage-like metallasilsesquioxanes in catalysis: A review

The review describes catalytic properties of a unique class of metal complexes—polycyclic cage-like metallasilsesquioxanes. Article is composed in retrospective manner and reflects the progress of the investigations in the field: from classic applications to recently discovered perspectives of cage-like metallasilsesquioxanes in catalysis of oxidation of С–H compounds. © 2016 Elsevier B.V.

Authors
Levitsky M.M.1 , Yalymov A.I.1 , Kulakova A.N. 1 , Petrov А.А.1 , Bilyachenko А.N. 1, 2
Journal
Journal of Molecular Catalysis A: Chemical
Publisher
Elsevier B.V.
Language
English
Pages
297-304
Status
Published
Link
External link
DOI
10.1016/j.molcata.2016.06.016
Volume
426
Year
2017
Organizations
  • 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str., 28, Moscow, 119991, Russian Federation
  • 2 People's Friendship University of Russia, Miklukho-Maklay Str., 6, Moscow, 117198, Russian Federation
Keywords
Cage metallasilsesquioxanes; Catalysis; Oxidation; Peroxides; С–H compound functionalization
Date of creation
19.10.2018
Date of change
28.06.2022
Short link
https://repository.rudn.ru/en/records/article/record/6217/
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