Transition-Metal Complexes of 4-Amino- and 4,6-Dihalopyrimidinoanthrones

Manganese(II), iron(III), cobalt(II), nickel(II), copper(II), zinc, and palladium(II) complexes of 4-amino-, 4-anilino-, 4-chloro-6-bromo-, and 4,6-dibromopyrimidinoanthrones were synthesized and isolated. As evident from infrared and electronic absorption spectroscopic data and the results of quantum-chemical calculations, the ligands coordinate to metal cations through the carbonyl oxygen atom and a ring nitrogen atom, unlike 2-amino derivatives of pyrimidinoanthrone (PA), which coordinate through a ring nitrogen atom only.

Editors
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Publisher
IAPC Nauka/Interperiodica
Number of issue
8
Language
English
Pages
1248-1252
Status
Published
Department
-
DOI
-
Number
-
Volume
44
Year
1999
Organizations
  • 1 Russ. Univ. of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
Keywords
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Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/572/