The first example of mechanochemical synthesis of organometallic pincer complexes

The synthesis of an organometallic PdII pincer complex is realized for the first time via C[sbnd]H bond activation of the bis(thiocarbamate) ligand with PdCl2(NCPh)2 under mechanochemical conditions either by grinding of the reactants in a mortar or in a vibration ball mill at gram scale. © 2017 Elsevier B.V.

Authors
Aleksanyan D.V. 1, 2 , Churusova S.G.1 , Aysin R.R.1 , Klemenkova Z.S.1 , Nelyubina Y.V.1 , Kozlov V.A.1
Journal
Inorganic Chemistry Communications
Publisher
Elsevier B.V.
Language
English
Pages
33-35
Status
Published
Link
External link
DOI
10.1016/j.inoche.2016.12.006
Volume
76
Year
2017
Organizations
  • 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russian Federation
  • 2 Organic Chemistry Department, Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
Keywords
Cyclometalation; Palladium; Pincer complexes; Solid-state synthesis
Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/5642/
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