Magnetic cage-like metallasilsesquioxanes

Magnetic Cage-like metallasilsesquioxanes (CLMSs) are made of paramagnetic transition metal ions (or lanthanides) assembled through silsesquioxane ligands to build molecular architectures of different structural organization. Numerous parameters govern the magnetic properties in such systems, which range from simple paramagnetic behaviour to slow relaxation of the magnetization. Here we present a short overview focusing on recent advances in this family of compounds giving an emphasis on their magnetic properties and trying to provide a property-structure relationship. (C) 2019 Elsevier B.V. All rights reserved.

Authors
Levitsky M.M. 1 , Bilyachenko A.N. 1, 2 , Shubina E.S. 1 , Long J. 3 , Guari Y. 3 , Larionova J. 3
Journal
Coordination Chemistry Reviews
Publisher
Elsevier B.V.
Language
English
Status
Published
DOI
10.1016/j.ccr.2019.213015
Number
UNSP 213015
Volume
398
Year
2019
Organizations
  • 1 Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia
  • 2 Peoples Friendship Univ Russia, Miklukho Maklaya Str 6, Moscow 117198, Russia
  • 3 Univ Montpellier, Team Ingn Mol & Nanoobjets, ICGM UMR 5253, CNRS,ENSCM, Pl E Bataillon, F-34095 Montpellier, France
Date of creation
24.12.2019
Date of change
24.12.2019
Short link
https://repository.rudn.ru/en/records/article/record/55628/
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