1,2-Bis(diphenylphosphino)ethane-containing commo-ferracarboranes of unusual structure

commo-Ferracarboranes [InlineEquation not available: see fulltext.] and [8-{(nido-7″,8″-C2B9H11-9″(11″)-)Ph2PCH2CH2PPh2}-commo-3,3′-Fe-{1,2-C2H9B10}{1′2′-C2B9H11}] were prepared as minor products in the metallation reaction of [K]+[nido-7,8-C2B9H12]− with the 14-electron iron complex [Ph2P(CH2)2PPh2]FeCl2. The structures of the complexes were determined by single-crystal X-ray diffraction. © 2019, Springer Science+Business Media, Inc.

Authors
Balagurova E.V.1 , Dolgushin F.M.1 , Tyurin A.P.2 , Smol’yakov A.F. 1, 3 , Chizhevsky I.T.1
Journal
Russian Chemical Bulletin
Number of issue
8
Language
English
Pages
1542-1547
Status
Published
Link
External link
DOI
10.1007/s11172-019-2589-x
Volume
68
Year
2019
Organizations
  • 1 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, Moscow, 119991, Russian Federation
  • 2 Gause Institute of New Antibiotics, 11 ul. Bolshaya Pirogovskaya, Moscow, 119021, Russian Federation
  • 3 Faculty of Science, Peoples’ Friendship University of Russia (RUDN University), 6 ul. Miklukho-Maklaya, Moscow, 117198, Russian Federation
Keywords
1,2-bis(diphenylphosphino)ethane; commo-ferracarboranes; molecular structure; ortho-cycloboro-nation
Date of creation
24.12.2019
Date of change
24.12.2019
Short link
https://repository.rudn.ru/en/records/article/record/55127/
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