Journal of Theoretical and Applied Information Technology.
Asian Research Publishing Network.
Vol. 95.
2017.
P. 5795-5804
Oxidation of C-H compounds with peroxides catalyzed by polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks: A review
Polynuclear transition metal complexes in Si- or Ge-sesquioxane frameworks synthesized in recent years turned out to be efficient catalysts in oxidation of organic compounds with peroxides: H2O2, tert-butyl hydroperoxide (TBHP), meta-chloroperoxybenzoic acid (MCPBA). This brief review describes oxygenations by peroxides of alkanes to alkyl hydroperoxides, alcohols and ketones and benzene to phenol as well as oxidation of alcohols to the corresponding ketones. Some reactions with MCPBA occur stereoselectively. © 2017 Elsevier B.V.
Authors
Levitsky M.M.1
,
Bilyachenko A.N.
1,
2
,
Shul'pin G.B.3,
4
Language
English
Pages
201-218
Status
Published
Link
Volume
849-850
Year
2017
Organizations
- 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Ulitsa Vavilova, Dom 28, Moscow, 119991, Russian Federation
- 2 People's Friendship University of Russia, Ulitsa Miklukho-Maklaya, Dom 6, Moscow, 117198, Russian Federation
- 3 Semenov Institute of Chemical Physics, Russian Academy of Sciences, Ulitsa Kosygina, Dom 4, Moscow, 119991, Russian Federation
- 4 Chair of Chemistry and Physics, Plekhanov Russian University of Economics, Stremyannyi Pereulok, Dom 36, Moscow, 117997, Russian Federation
Keywords
Alcohols; Alkanes; Alkyl hydroperoxides; Hydrogen peroxide; meta-Chloroperoxybenzoic acid (MCPBA); Stereoselectivity
Date of creation
19.10.2018
Date of change
19.10.2018
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